Bulletin of the Faculty of Agriculture, Shimane University

Faculty of Agriculture, Shimane University

ISSN:0370-940X

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Use this link to cite this item : https://ir.lib.shimane-u.ac.jp/1797

Bulletin of the Faculty of Agriculture, Shimane University 18

1984-12-20 発行

酵素的塩基交換反応を利用したチアミンアナログの調製

Enzymic Preparation of Thiamine Analogues by the Utilization of a Base-Exchange Reaction

Mochida, Kazuo

Nakamura, Toshiie

Fujita, Keiji

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The enzymic preparation of thiamine analogues was examined. Thiaminase I catalyzes an exchange reaction of the thiazole moiety of thiamine with aniline, pyridine, cysteine etc., liberating 2-hydroxyalkyl-4-methyl-5-β-hydroxyethylthiazole. Ten kinds of（2-methyl -4-amino-5-pynmidinyl）methyl derivatives(Pm derivatives) were preparated by the uti lization of the base-exchange reaction of free or Sepharose 4B-immobilized thiaminase I. Pm derivatives isolated were Pm-thiophenol, Pm-o-aminothiophenol, Pm-benzoic acid, Pmaniline, Pm-pyridine, Pm-α-pycoline, Pm-nicotinamide, Pm-quinoline, Pm-pyperidine, and Pm-cysteine. The physicochemical parameters of these compounds were determined.

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NCID

AN00108015

d0030018n026.pdf 700 KB

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