Bulletin of the Faculty of Agriculture, Shimane University

Faculty of Agriculture, Shimane University

ISSN:0370-940X

number of downloads : ?

Use this link to cite this item : https://ir.lib.shimane-u.ac.jp/1797

Bulletin of the Faculty of Agriculture, Shimane University 18

1984-12-20 発行

酵素的塩基交換反応を利用したチアミンアナログの調製

Enzymic Preparation of Thiamine Analogues by the Utilization of a Base-Exchange Reaction

Mochida, Kazuo

Nakamura, Toshiie

Fujita, Keiji

File

d0030018n026.pdf 700 KB

Description

The enzymic preparation of thiamine analogues was examined. Thiaminase I catalyzes an exchange reaction of the thiazole moiety of thiamine with aniline, pyridine, cysteine etc., liberating 2-hydroxyalkyl-4-methyl-5-β-hydroxyethylthiazole. Ten kinds of（2-methyl -4-amino-5-pynmidinyl）methyl derivatives(Pm derivatives) were preparated by the uti lization of the base-exchange reaction of free or Sepharose 4B-immobilized thiaminase I. Pm derivatives isolated were Pm-thiophenol, Pm-o-aminothiophenol, Pm-benzoic acid, Pmaniline, Pm-pyridine, Pm-α-pycoline, Pm-nicotinamide, Pm-quinoline, Pm-pyperidine, and Pm-cysteine. The physicochemical parameters of these compounds were determined.

About This Article

d0030018n026.pdf 700 KB

Other Article

On Anomalous Segregation of Culm Length and Heading Time Observed in the Rice Variety "Nipponbare"(II) : Outcrossing Percentages of the Rice Variety "Nipponbare"/

PP. 1 - 7

Effects of Light Intensity around Cluster on the Coloration and Pigmentation in 'Kyoho' Grape/

PP. 8 - 15

Effect of Dormancy-breaking Treatments on Respiration of Gladiolus Corms/

PP. 16 - 20

Studies on the Flower Production of Bulbous Plants under Computer Controlled System(6) : On the Growth of Retarded Lily Plant cv. 'Enchantment' and the Quality and Keeping of Its Cut Flowers/

PP. 21 - 27

The variation of Rumination Behaviour in Sheep/

PP. 28 - 33

The Nitrogen Utilization in Sheep Receiving Forage Diet in the Fresh Form/

PP. 34 - 39

On the Reasonable Shape of Hoofs in Beef Cattle (Late Stage of Fattening) and Effect of Trimming on Fattening/

PP. 40 - 45

Recovery of Buried Juvenile Sugi(Cryptomeria japonica D. Don) Trees after Melting of Snow(I) : On the Occasion of Two Years Old Plantation in the Year with Little Snow/

PP. 46 - 52

Studies on Mineral Cycling in a Deciduous Broad-leaved Forest at Sanbe Forest of Shimane University(XII) : Difference of Above Ground Biomass in a Deciduous Broad-leaved Forest along a Slope/

PP. 53 - 60

The Composition and Above Ground Biomass of Understory in a Deciduous Broad-leaved Forest/

PP. 61 - 66

Studies for Management of Deciduous Broad Leaved Forest in Sanbe University Forest(1) : The Present Stand Structure and the Problems of Further Studies/

PP. 67 - 73

Impact Sound Insulathion of Wooden Panel Floor/

PP. 74 - 79

Survey of Impact Noise Isolation Capability of Floors in a Reinforced-Concrete Apartment Building/

PP. 80 - 87

Studies on the Conversion of Wood into Energy(I) : Chemical Composition and Calorific Value of Extracts from Paraquat-treated Wood/

PP. 88 - 93

Surface-Densification of Wood by Continuous Hot-Pressing/

PP. 94 - 101

Species Identification and Microscopic Structure of Wood Artifacts Excavated from the Remains of Sainotoge and Nishikawatsu/

PP. 102 - 112

Effect of Growth Temperature on Lipid and Fatty Acid Compositions in Photosynthetic Bacterium, Rhodopseudomonas sphaeroides S/

PP. 113 - 119

Rainfall and Runoff Characteristics in Masuda Reclamation Area Caused by Heavy Rainfall, July, 1983/

PP. 120 - 131

Distribution Characteristics of Ordered Stream Numbers in Stream Network Systems/

PP. 132 - 142

Time Series Analysis of the Salinity of Shinjiko Lake and Related Hydrological Observations(I) : Abstructs of the Variations and Correlations by Monthly Observations/

PP. 143 - 149

Experimental Study of Consolidation of Compacted Partially Saturated Soils(II)/

PP. 150 - 158

On the Dimensions of Tractor on the Slope Field(3) : Relation between Yaw Angle and Side Slip Angle/

PP. 159 - 163

Noise Analysis in Rice Drying, Processing and Storage Facilities Mesurement of Noisy Sound in Kanan and Hokubu Country Elevators, Izumo City/

PP. 164 - 170

Scanning Electron-Microscopy of Sterigma in Exobasidium spp./

PP. 171 - 182

Pathogenicity of Pyricularia sp. from Bamboo and P. oryzae to Bamboo Grown in the Fields/

PP. 183 - 187

Enzymic Preparation of Thiamine Analogues by the Utilization of a Base-Exchange Reaction/

PP. 188 - 192

Automatic Determination of Thiamine and Its Phosphates by the Use of Immobilized Thiaminase I/

PP. 193 - 196

The Present Conditions and Problems of the Large-Scale Tenant Farmers of Rice Production/

PP. 197 - 205

Process of Development of the Tenryu Forestry/

PP. 206 - 213