Title Transcription | ハロゲンカ スズ 2 ノ サクカゴウブツ ノ メスバウア ケンキュウ
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Title Alternative (English) | Mossbauer Study of the Complex Compounds of Tin(II) Halides
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File | |
language |
eng
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Author |
Mishima, Mitsuo
Idogaki, Masatoshi
Negita, Hisao
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Description | Mossbauer spectra of <119>^Sn were observed in tin (II) chloride, bromide and their complexes of the types MSnX^3・H_20 and M_2SnX_4・H_20, where M = NH_4, K or Cs, and X = Cl or Br. All of the complexes exhibited small quadrupole splittings. In comparison with the parent halides SnX_2, the complex chlorides have smaller isomer shifts, whereas this is not the case for the complex bromides. The isomer shift was related to the strength of the ligand field, and the decrease in the isomer shift was interpreted by s-p mixing due to the field stabilization.
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Journal Title |
Memoirs of the Faculty of Literature and Science, Shimane University. Natural sciences
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Volume | 7
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Start Page | 73
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End Page | 77
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ISSN | 03709434
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Published Date | 1974-03-10
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NCID | AN0010806X
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Publisher | 島根大学文理学部
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Publisher Aalternative | The Faculty of Literature and Science, Shimane University
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NII Type |
Departmental Bulletin Paper
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OAI-PMH Set |
Faculty of Science and Engineering
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他の一覧 |