| File | |
| language |
eng
|
| Author |
Tanaka, Hidekazu
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University
Inoue, Masahiko
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University
Ishikawa, Tatsuo
School of Chemistry, Osaka University of Education
Nakayama, Takenori
Materials Research Laboratory, Kobe Steel, LTD.
|
| Description | For simulation of the atmospheric corrosion of steel in a coastal industrial district, β-FeOOH rusts were synthesized by aging the aqueous FeCl_3 solutions containing SO_3^<2->. The yield and crystallite size of β-FeOOH were remarkably decreased by adding SO_3^<2->, implying the suppression of formation and crystallization of β-FeOOH. Before aging, added SO_3^<2-> broke the coordination of Cl^- and OH^- to Fe_<3+> in Fe^<3+>-complexes and reduced the Fe^<3+> to Fe^<2+>. These facts suppose that SO_3^<2-> generated by dissolution of SO_X gas in thin film water on the steels at a coastal industrial zone markedly inhibits the formation of β-FeOOH rust.
|
| Subject | A. Steel
A. Iron
B. X-ray diffraction
C. Atmospheric corrosion
C. Rust
|
| Journal Title |
Corrosion science
|
| Volume | 112
|
| Start Page | 241
|
| End Page | 245
|
| ISSN | 0010938X
|
| Published Date | 2016-11
|
| DOI | |
| DOI Date | 2017-12-01
|
| NCID | AA0061968X
|
| Publisher | Elsevier
|
| NII Type |
Journal Article
|
| Format |
PDF
|
| Rights | © 2016 Elsevier Ltd. All rights reserved.
The full-text file will be made open to the public on December 1, 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
|
| Text Version |
著者版
|
| OAI-PMH Set |
Interdisciplinary Graduate School of Science and Engineering
|
