| File | |
| language |
eng
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| Author |
Oka, Marina
Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan
Katsube, Daichi
Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan
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| Description | Inspired by the photochemical mechanism of a plant blue-light receptor, a unique flavin-based photocatalytic system was developed for the chemoselective heterocoupling of two different thiols, which enabled the facile synthesis of unsymmetrical disulfides. Owing to the redox- and photo-organocatalysis of flavin, the coupling reaction took place under mild metal-free conditions and visible light irradiation with the use of air, which is recognized as the ideal green oxidant.
|
| Subject | Disulfides
Flavins
Thiols,Adducts
Heterocouplings
|
| Journal Title |
Organic Letters
|
| Volume | 22
|
| Issue | 23
|
| Start Page | 9244
|
| End Page | 9248
|
| ISSN | 1523-7060
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| Published Date | 2020-12-04
|
| DOI | |
| Publisher | American Chemical Society
|
| NII Type |
Journal Article
|
| Format |
PDF
|
| Text Version |
著者版
|
| Gyoseki ID | 38961
|
| OAI-PMH Set |
Faculty of Science and Engineering
|
