| Title Transcription | ユウキ キンゾク サクタイ ノ UV ト ESR スペクトル 2 バナジルイオン ト ハイドロキサムサン ノ ハンノウ
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| Title Alternative (English) | UV & ESR Spectra of Organometallic Complexes(II) : Reaction of Vanadyl lon with Hydroxamic Acids
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| File | |
| language |
jpn
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| Author |
Sogabe, Kunihisa
Nakanishi, Yasue
Fujita, Reiko
Takahashi, Taidou
Hara, Kazuo
Murakami, Ryusei
Sakamoto, Ikko
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| Description | UV and ESR Spectra of organometallic complexes formed by the reaction of vanadyl ion with various hydroxamic acids in dioxane were observed. These results reflect the good relationship between planarity of complexes and vanadyl hyperfine coupling constants. Vanadyl-hydroxamic acid complexes prefer planar tetra-coordination comfomation are seem to show the similar behavior as copper-hydroxamic acid complexes. However, by one-electron oxidation, vanadyl ions produced corresponding nitroxide radicals in hydroxamic acids. The ability of vanadyl ion for radical production is suggested to be involved in the similar mechanism detected in metabolism.
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| Journal Title |
Memoirs of the Faculty of Education, Shimane University. Natural science
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| Volume | 24
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| Issue | 1
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| Start Page | 21
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| End Page | 25
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| ISSN | 05869943
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| Published Date | 1990-07-31
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| NCID | AN00107941
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| Publisher | 島根大学教育学部
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| Publisher Aalternative | The Faculty of Education Shimane University
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| NII Type |
Departmental Bulletin Paper
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| OAI-PMH Set |
Faculty of Education
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| 他の一覧 |
