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language
eng
Author
Mishima, Mitsuo
Description
Temperature dependence of 35Cl NQR frequencies in TeCl4・POCl3 giving six NQR lines was observed in the range of 77 K to 400 K. Three of the NQR iines faded out near 285 K and the others could be detected up to 360 K. The Zeeman effect on the resonance lines was examined at 253 K using a single crystal. Each of these lines gave a single zero-splitting pattern and all the asymmetry parameters for these lines were negligibly small. On the basis of the crystal symmetry and the orientations of the Te-Cl and P-Cl bonds, the moiecular structure of the title compound was deduced and the assignment of the NQR lines was performed with the aid of a CND0/2 MO calcuiation.
Journal Title
Bulletin of Shimane Medical University
Volume
25
Start Page
1
End Page
5
ISSN
03879097
Published Date
2002-12-01
NCID
AN00107602
Publisher
島根医科大学
Publisher Aalternative
Shimane Medical University
NII Type
Departmental Bulletin Paper
OAI-PMH Set
Faculty of Medicine
Remark
http://ci.nii.ac.jp/vol_issue/nels/AN00107602_jp.html
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