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language
eng
Author
Mishima, Mitsuo
Description
35Cl NQR spectra in SnCl4.DME have been observed in the range of 77 K to 420 K. Two NQR lines have been detected at the temperatures above 96 K and a single line at 77 K. Three crystal modifications of SnCl4.DME have been found. A trans geometry is suggested for one of them. The Zeeman effect on a single crystal of SnCl4.DME has been studied at room temperature. It is revealed on the basis of the orientations of the z axes of the electric field gradient that the molecule of SnCl4.DME has a cis geometry at room temperature. The higher-frequency line is assigned to the axial Cl atoms and the lower-frequency one to the equatorial Cl atoms. The asymmetry parameters
for the Cl atoms contributing to the higher- and lower-frequency lines are 0.038 and 0.099, respectively.
Journal Title
島根大学医学部紀要
Volume
28
Start Page
1
End Page
6
ISSN
1880084X
Published Date
2005-12-01
NCID
AA12049432
Publisher
島根大学医学部
Publisher Aalternative
Shimane University Faculty of Medicine
NII Type
Departmental Bulletin Paper
Format
PDF
Text Version
出版社版
OAI-PMH Set
Faculty of Medicine
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