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language
eng
Author
Mishima, Mitsuo
Description
In 2,4,6-trichloroanisole, three ^<35>Cl NQR lines were observed in the range of 77 K to the melting point. The Zeeman effect on each resonance line was examined at room temperature using a single crystal. The values of the asymmetry parameters for the two higher-frequency lines were ca. 0.12, whereas that for the lower-frequency line was 0.08. The angles between the C-Cl bonds were estimated to be 117.7°, 119.0°, and 123.4° on the basis of the orientations of the axes of the electric field gradients. The two higher-frequency lines were assigned to the chlorine atoms at the ortho positions and the lower frequency line to the chlorine atom at the para position on the basis of the angles between the C-Cl bond angles and the asymmetry parameters.
Subject
NQR
Zeeman effect
trichloroanisole
Journal Title
Bulletin of Shimane Medical University
Volume
21
Start Page
41
End Page
44
ISSN
03879097
Published Date
1998-12-01
NCID
AN00107602
Publisher
島根医科大学
NII Type
Departmental Bulletin Paper
Format
PDF
Text Version
出版社版
OAI-PMH Set
Faculty of Medicine
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