| Title Transcription | アミンボラン カゴウブツ ノ リッタイ ソウゴ サヨウ ニ ツイテ
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| Title Alternative (English) | A Study on Steric Interactions of Amine Borane Compounds
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| File | |
| language |
eng
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| Author |
Sogabe, Kunihisa
Kohno, Michifumi
Katoh, Hideko
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| Description | Chemical shifts of methyl group in amine boranes, <(CH_3)>_<3-n>H_nN･BF_3 and (CH_3)_3N･BX_3 (X = H, F, Cl, Br...) were larger than those of o-halotoluenes, o-XC_6 H_4 CH_3. It is explained by differences in steric effects between <sp>^3 bybrid in amine boranes and <sp>^2 bybrid in o-halotoluenes and by a number of methyl groups and halogen atoms. The facts that larger Van der Waals radius of halogen atoms make the B-N bond length shorter in the haloborazines B_3N_3H_3X_3 and amine boranes are explained by the steric effect based on sp^3 hybrid.
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| Journal Title |
Memoirs of the Faculty of Education, Shimane University. Natural science
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| Volume | 14
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| Start Page | 1
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| End Page | 4
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| ISSN | 05869943
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| Published Date | 1980-12-25
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| NCID | AN00107941
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| Publisher | 島根大学教育学部
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| Publisher Aalternative | The Faculty of Education Shimane University
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| NII Type |
Departmental Bulletin Paper
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| OAI-PMH Set |
Faculty of Education
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| 他の一覧 |
