| Title Transcription | イオン ト ヨウバイ ノ ソウゴ サヨウ ニ カンスル ケンキュウ 6 アセチルアセトン チュウ ノ カドミウム イオン タヨウバイ カン サク セイセイ ハンノウ ト ソノ ヨウバイ カン イコウ ギブス ジユウ エネルギー
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| Title Alternative (English) | Studies on lon-solvent Interactions(VI) : The Complexing of the Cadmium lon in Acetylacetone with Other Solvents and Its Gibbs Free Energy of Transfer
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| File | |
| language |
eng
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| Author |
Sakamoto, Ikko
Sogabe, Kunihisa
Yamane, Narihiro
Hiroe, Yasunori
Okazaki, Satoshi
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| Description | The complex formation constants (βn) of the cadmium ion in acetylacetone (2, 4-pentanedione, Hacac) with other solvents S and its Gibbs free energies of transfer (ΔG^0_<tr>) have been detennined polarographically. The values of ΔG^0_<tr>(Cd^<2+> : Hacac→S) (in kJ mol^<-1>) and βn, where n is the maximum coordination number detected, are as follows; -9.7 and log β_4 = 2.53 for acetone, -45.5 and log β_6 = 4.63 for water, -24.3 and log β_5 = 3.20 for EtOH, -85.3 and log β_5 = 7.63 for N, N-dimethylformamide, -83.7 and log β_6 = 8.22 for N, N-dimethylacetamide, and -110.0 and log β_8 = 12.7 for dimethyl sulfoxide. The correlation between the ΔG^0_<tr> and βn values is discussed on the basis of the coordination model of ionic solvation. The results for the cadmium ion are shortly discussed in comparison with those for the silver and sodium ions.
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| Journal Title |
Memoirs of the Faculty of Education, Shimane University. Natural science
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| Volume | 23
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| Issue | 1
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| Start Page | 43
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| End Page | 52
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| ISSN | 05869943
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| Published Date | 1989-07-25
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| NCID | AN00107941
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| Publisher | 島根大学教育学部
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| Publisher Aalternative | The Faculty of Education Shimane University
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| NII Type |
Departmental Bulletin Paper
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| OAI-PMH Set |
Faculty of Education
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| 他の一覧 |
