| language |
jpn
|
| Title Transcription | ゾル ゲル ホウ ニ ヨル アンチモン サン ヨウ イオン コウカン マク ノ サクセイ
|
| Title Alternative (English) | Preparation of Antimony1 Acid Cation-Exchange Membranes by Using Sol-Gel Method
|
| Author |
KOGURE, Makoto
Analytical Chemistry, Showa College of Phar m aceutical Siences
TANAKA, Tatsuo
Analytical Chemistry, Showa College of Phar m aceutical Siences
YASUJIMA, Satoshi
Analytical Chemistry, Showa College of Phar m aceutical Siences
SUZUKI, Takashi
Applied Chemistry and Biological Technology, Faculty of Engineering, Yamanashi University
OHYA, Haruhiko
Department of Material Science and Chemical Engineering, Yokohama National University
|
| Description | A new inorganic cation-exchange membrane was successfully prepared on a microporous alumina substrate by dipcoating an antimonic acid sol solution obtained from a mixture of antimonic acid sol: Si(OC2H5)4: H2O: C2H5OH: HCl=O.06: 1: 11: 6.8: 0.068 in molar ratio.
The thickness, resistivity and ion-exchange capacity of the membrane increased with an increase in the number of dipcoated times, while the limiting currnet density showed a tendency to decrease. The ion-exc hange capacity, area resistivity, limiting current density and transport number of Na+ for the 10 times coated membrane were O.0061 meq·cm-2, 186.2 Ω·cm2, 0.96 A·dm-2and O.70, respectively. The mem branes could stand in 6 M hydrochloric acid or nitric acid aqueous solution at 80°C for 24 h without any change in ion-exchange capacity. |
| Journal Title |
NIPPON KAGAKU KAISHI
|
| Volume | 1991
|
| Issue | 12
|
| Start Page | 1618
|
| End Page | 1623
|
| ISSN | 0369-4577
|
| ISSN（Online） | 2185-0925
|
| Published Date | 1991-12-10
|
| DOI | |
| Publisher | （社）日本化学会
|
| Publisher Transcription | シャダンホウジン ニホン カガク カイ
|
| Publisher Aalternative | The Chemical Society of Japan
|
| NII Type |
Journal Article
|
| OAI-PMH Set |
Faculty of Life and Environmental Science
|
