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Title Transcription
ユウキ カゴウブツ チュウ ニ ショウジタ ラジカル ノ ケンキュウ 1 イミノキシラジカル ノ ESR スペクトル
Title Alternative
A Study of Radicals Produced in Organic Compounds(I) : ESR Spectra of Iminoxy Radicals
File
language
jpn
Author
Sogabe, Kunihisa
Yoneda, Kazuo
Koshino, Kazutane
Ishikawa, Junji
Takahashi, Taidou
Hara, Kazuo
Sakamoto, Ikko
Description
One-electron oxidation occurred simultaneously on the formation of copper (II), ferric(II) or oxovanadium(II) complexes with oximes and related compounds produces iminoxy radicals. These iminoxy radicals are stable in complexes with metal ions but change into another radical which produced by Beckmann rearrangement reaction of oxime under acidic condition. These results reflect that reactivity of oximes and aldoximes are affected by molecular structure and oxide or metal ion Behavior of radicals produced in the reaction such as Beckmann rearrangement is suggested to be involved in the similar mechanism detected in metabolism.
Journal Title
Memoirs of the Faculty of Education, Shimane University. Natural science
Volume
25
Start Page
7
End Page
12
ISSN
05869943
Published Date
1991-12-25
NCID
AN00107941
Publisher
島根大学教育学部
Publisher Aalternative
The Faculty of Education Shimane University
NII Type
Departmental Bulletin Paper
OAI-PMH Set
Faculty of Education
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