| File | |
| Title |
Coupled Flavin-Iodine Redox Organocatalysts: Aerobic Oxidative Transformation from N-Tosylhydrazones to 1,2,3-Thiadiazoles
|
| Creator |
Ishikawa Tatsuro
Kimura Maasa
Kumoi Takuma
|
| Source Title |
ACS Catalysis
|
| Volume | 7 |
| Issue | 8 |
| Start Page | 4986 |
| End Page | 4989 |
| Journal Identifire |
ISSN 2155-5435
|
| Descriptions |
A bioinspired two-component redox organocatalyst system using 1,10-bridged flavinium and NH4I was developed to perform environmentally friendly aerobic oxidative ring formation of 1,2,3-thiadiazoles from N-tosylhydrazones and sulfur. The redox organocatalysis of the flavinium promoted the iodine-catalyzed system without the use of any sacrificial reagents, except for environmentally benign molecular oxygen.
|
| Subjects |
redox organocatalyst
flavin
iodine
aerobic oxidation
thiadiazole
|
| Language |
eng
|
| Resource Type | journal article |
| Publisher |
American Chemical Society
|
| Date of Issued | 2017-6-29 |
| Rights |
Copyright © 2017 American Chemical Society
|
| Publish Type | Accepted Manuscript |
| Access Rights | open access |
| Relation |
[DOI] 10.1021/acscatal.7b01535
[URI] https://pubs.acs.org/journal/accacs
|
| Remark | ACS Catal. 2017, 7, 8, 4986-4989 Publication Date:June 29, 2017 |
