固体有機酸およびアルカリ・リグニン官能基の赤外スペクトルによる定量法と反応性の追跡

島根大学農学部研究報告 Volume 1 Page 125-134 published_at 1967-12
アクセス数 : 1029
ダウンロード数 : 763

今月のアクセス数 : 73
今月のダウンロード数 : 2
File
d0030001n021.pdf 1.28 MB エンバーゴ : 2002-06-13
Title
固体有機酸およびアルカリ・リグニン官能基の赤外スペクトルによる定量法と反応性の追跡
Title
Reactivity of the Functional groups in the Solid Organic Acids and the Alkali-lignins traced by the Infrared Spectrographic Method
Title Transcription
コタイ ユウキサン オヨビ アルカリ リグニン カンノウキ ノ セキガイ スペクトル ニヨル テイリョウホウ ト ハンノウセイ ノ ツイセキ
Creator
Fukuwatari Shichiro
Source Title
島根大学農学部研究報告
Bulletin of the Faculty of Agriculture, Shimane University
Volume 1
Start Page 125
End Page 134
Journal Identifire
ISSN 0370940X
Descriptions
(1) The chemical reactivity of the carboxyl groups of the solid organic acids could be traced comparative-quantitatively by the infrared spectrometric method.
(2) The absorption bands of 1720-1700<cm>^<-1> shown by the alkali-lignins was assigned to the carbonyl stretching vibrations of the carboxyl groups.
(3) The carboxyl groups of alkali-lignin did not give the shift absorption band near 1550<cm>^<-1>, even when neutralized completly by sodium hydroxide solution.
(4) The phenolic absorption bands near 1200<cm>^<-1> of ferulic acid was disappeared by the neutralization, but these phenomena could not be found in the spectrum of the alkali-lignins.
(5) The tracing curves of the neutralization of these solid acids, stearic acid and ferulic acid, as well as, cinnamic acid and lignin carbonic acid were drawn on the smilar lines in these experiments.
Language
jpn
Resource Type departmental bulletin paper
Publisher
島根大学農学部
Date of Issued 1967-12
Publish Type Version of Record
Access Rights open access
Relation
[NCID] AN00108015