| File | |
| Title |
ハロゲン化スズ(II)の錯化合物のメスバウア研究
|
| Title |
Mossbauer Study of the Complex Compounds of Tin(II) Halides
|
| Title Transcription |
ハロゲンカ スズ ２ ノ サクカゴウブツ ノ メスバウア ケンキュウ
|
| Creator |
Idogaki Masatoshi
Negita Hisao
|
| Source Title |
島根大学文理学部紀要. 理学科編
Memoirs of the Faculty of Literature and Science, Shimane University. Natural sciences
|
| Volume | 7 |
| Start Page | 73 |
| End Page | 77 |
| Journal Identifire |
ISSN 03709434
|
| Descriptions |
Mossbauer spectra of <119>^Sn were observed in tin (II) chloride, bromide and their complexes of the types MSnX^3・H_20 and M_2SnX_4・H_20, where M = NH_4, K or Cs, and X = Cl or Br. All of the complexes exhibited small quadrupole splittings. In comparison with the parent halides SnX_2, the complex chlorides have smaller isomer shifts, whereas this is not the case for the complex bromides. The isomer shift was related to the strength of the ligand field, and the decrease in the isomer shift was interpreted by s-p mixing due to the field stabilization.
|
| Language |
eng
|
| Resource Type | departmental bulletin paper |
| Publisher |
島根大学文理学部
The Faculty of Literature and Science, Shimane University
|
| Date of Issued | 1974-03-10 |
| Access Rights | open access |
| Relation |
[NCID] AN0010806X
|
