Non-Covalently Immobilized Chiral Imidazolidinone on Sulfated-Chitin: Reusable Heterogeneous Organocatalysts for Asymmetric Diels-Alder Reaction

Advanced Synthesis & Catalysis Volume 162 Issue 1 published_at 2019-11-12
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Title
Non-Covalently Immobilized Chiral Imidazolidinone on Sulfated-Chitin: Reusable Heterogeneous Organocatalysts for Asymmetric Diels-Alder Reaction
Creator
Watanabe Mirai
Sakai Takuya
Oka Marina
Makinose Yuki
Miyazaki Hidetoshi
Source Title
Advanced Synthesis & Catalysis
Volume 162
Issue 1
Journal Identifire
ISSN 1615-4169
Descriptions
A heterogeneous chiral imidazolodinone catalyst was synthesized by immobilization on a sulfated
chitin through non-covalent ionic interactions. The chitin-based organocatalyst promoted the asymmetric Diels-Alder reaction with high enantioselectivity under heterogeneous conditions and was successfully reused multiple times without apparent loss of catalytic activity and enantioselectivity.
Subjects
Organocatalysis ( Other)
heterogeneous catalysis ( Other)
asymmetric Diels-Alder reaction ( Other)
imidazolidinone ( Other)
chitin ( Other)
Language
eng
Resource Type journal article
Publisher
Wiley
Date of Issued 2019-11-12
Rights
This is the peer reviewed version of the following article: https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201901036, which has been published in final form at https://doi.org/10.1002/adsc.201901036. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Publish Type Accepted Manuscript
Access Rights open access
Relation
[DOI] 10.1002/adsc.201901036
[URI] https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201901036