| File | |
| Title |
Influence of anions on the structure and morphology of steel rust particles prepared by aerial oxidation of acidic Fe(II) solutions
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| Creator |
Hatanaka Nagisa
Muguruma Miya
Nishitani Ayaka
Ishikawa
Nakayama Takenori
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| Source Title |
Advanced powder technology
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| Volume | 27 |
| Issue | 5 |
| Start Page | 2291 |
| End Page | 2297 |
| Journal Identifire |
ISSN 09218831
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| Descriptions |
In order to simulate the atmospheric corrosion of steel, artificial steel rust particles were synthesized by aerial oxidation of aqueous solutions containing FeCl_2, FeSO_4 and NaNO_3, and the structure and morphology of the obtained particles were characterized by XRD and TEM. Needle-like SO_4^<2-> containing Schwertmannite (Fe_8O_8(OH)_6(SO_4)) particles were mainly formed in FeCl_2－FeSO_4, FeSO_4－NaNO_3, FeCl_2－FeSO_4－NaNO_3 systems, and the crystallization and particle growth of this material were not influenced by added Cl^- and NO_3^-. The rod-shaped β-FeOOH particles were formed from in only FeCl_3-NaNO_3 system, though no marked change in crystallite and particle sizes of the β-FeOOH was recognized by adding NO_3^-. Accordingly, it can be suggested that the corrosive SO_X gas and air-borne chloride strongly affect the rust formation in atmospheric corrosion of the steels.
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| Subjects | |
| Language |
eng
|
| Resource Type | journal article |
| Publisher |
Society of Powder Technology, Japan
粉体工学会
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| Date of Issued | 2016-09 |
| Rights |
©︎ 2016 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. This is an open access article under the CC BY-NC-ND license (http://creativecommons. org/licenses/by-nc-nd/4.0/).
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| Publish Type | Accepted Manuscript |
| Access Rights | open access |
| Relation |
[DOI] 10.1016/j.apt.2016.09.004
[NCID] AA1074214X
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