| File | |
| Title |
有機化合物中に生じたラジカルの研究(I) : イミノキシラジカルのESRスペクトル
|
| Title |
A Study of Radicals Produced in Organic Compounds(I) : ESR Spectra of Iminoxy Radicals
|
| Title Transcription |
ユウキ カゴウブツ チュウ ニ ショウジタ ラジカル ノ ケンキュウ 1 イミノキシラジカル ノ ESR スペクトル
|
| Creator |
Yoneda Kazuo
Koshino Kazutane
Ishikawa Junji
Hara Kazuo
|
| Source Title |
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
|
| Volume | 25 |
| Start Page | 7 |
| End Page | 12 |
| Journal Identifire |
ISSN 05869943
|
| Descriptions |
One-electron oxidation occurred simultaneously on the formation of copper (II), ferric(II) or oxovanadium(II) complexes with oximes and related compounds produces iminoxy radicals. These iminoxy radicals are stable in complexes with metal ions but change into another radical which produced by Beckmann rearrangement reaction of oxime under acidic condition. These results reflect that reactivity of oximes and aldoximes are affected by molecular structure and oxide or metal ion Behavior of radicals produced in the reaction such as Beckmann rearrangement is suggested to be involved in the similar mechanism detected in metabolism.
|
| Language |
jpn
|
| Resource Type | departmental bulletin paper |
| Publisher |
島根大学教育学部
The Faculty of Education Shimane University
|
| Date of Issued | 1991-12-25 |
| Access Rights | open access |
| Relation |
[NCID] AN00107941
|
