| File | |
| Title |
有機金属錯体のUVとESRスペクトル(II) : バナジルイオンとハイドロキサム酸の反応
|
| Title |
UV & ESR Spectra of Organometallic Complexes(II) : Reaction of Vanadyl lon with Hydroxamic Acids
|
| Title Transcription |
ユウキ キンゾク サクタイ ノ UV ト ESR スペクトル 2 バナジルイオン ト ハイドロキサムサン ノ ハンノウ
|
| Creator |
Nakanishi Yasue
Fujita Reiko
Hara Kazuo
Murakami Ryusei
|
| Source Title |
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
|
| Volume | 24 |
| Issue | 1 |
| Start Page | 21 |
| End Page | 25 |
| Journal Identifire |
ISSN 05869943
|
| Descriptions |
UV and ESR Spectra of organometallic complexes formed by the reaction of vanadyl ion with various hydroxamic acids in dioxane were observed. These results reflect the good relationship between planarity of complexes and vanadyl hyperfine coupling constants. Vanadyl-hydroxamic acid complexes prefer planar tetra-coordination comfomation are seem to show the similar behavior as copper-hydroxamic acid complexes. However, by one-electron oxidation, vanadyl ions produced corresponding nitroxide radicals in hydroxamic acids. The ability of vanadyl ion for radical production is suggested to be involved in the similar mechanism detected in metabolism.
|
| Language |
jpn
|
| Resource Type | departmental bulletin paper |
| Publisher |
島根大学教育学部
The Faculty of Education Shimane University
|
| Date of Issued | 1990-07-31 |
| Access Rights | open access |
| Relation |
[NCID] AN00107941
|
