| File | |
| Title |
アミンボラン化合物の立体相互作用について
|
| Title |
A Study on Steric Interactions of Amine Borane Compounds
|
| Title Transcription |
アミンボラン カゴウブツ ノ リッタイ ソウゴ サヨウ ニ ツイテ
|
| Creator |
Kohno Michifumi
Katoh Hideko
|
| Source Title |
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
|
| Volume | 14 |
| Start Page | 1 |
| End Page | 4 |
| Journal Identifire |
ISSN 05869943
|
| Descriptions |
Chemical shifts of methyl group in amine boranes, <(CH_3)>_<3-n>H_nN･BF_3 and (CH_3)_3N･BX_3 (X = H, F, Cl, Br...) were larger than those of o-halotoluenes, o-XC_6 H_4 CH_3. It is explained by differences in steric effects between <sp>^3 bybrid in amine boranes and <sp>^2 bybrid in o-halotoluenes and by a number of methyl groups and halogen atoms. The facts that larger Van der Waals radius of halogen atoms make the B-N bond length shorter in the haloborazines B_3N_3H_3X_3 and amine boranes are explained by the steric effect based on sp^3 hybrid.
|
| Language |
eng
|
| Resource Type | departmental bulletin paper |
| Publisher |
島根大学教育学部
The Faculty of Education Shimane University
|
| Date of Issued | 1980-12-25 |
| Access Rights | open access |
| Relation |
[NCID] AN00107941
|
