ホウ素化合物のNMR研究

島根大学教育学部紀要. 自然科学 Volume 11 Page 13-17 published_at 1977-12-25
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Title
ホウ素化合物のNMR研究
Title
A NMR Study on Boron Compounds
Title Transcription
ホウソ カゴウブツ ノ NMR ケンキュウ
Creator
Source Title
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
Volume 11
Start Page 13
End Page 17
Journal Identifire
ISSN 05869943
Descriptions
^1H NMR spectra of amine borane, <(CH_3)>_<3-n> H_nN・BH_3 and amine boron trifluoride, <(CH_3)>_<3-n>H_nN・BF_3 adducts were observed. ^1H chemical shifts of methyl groups occur at a higher field as the methyl group successively substituted for hydrogen on nitrogen. With respect to trimethylamine, both BH_3 and BF_3 bases are considered to be comparable acids. These results lead to a good relation between chemical shifts in BF_3 group and variations in structure on amine boron trifluoride adducts.
Language
eng
Resource Type departmental bulletin paper
Publisher
島根大学教育学部
The Faculty of Education Shimane University
Date of Issued 1977-12-25
Access Rights open access
Relation
[NCID] AN00107941