File | |
Title |
ホウ素化合物のNMR研究
|
Title |
A NMR Study on Boron Compounds
|
Title Transcription |
ホウソ カゴウブツ ノ NMR ケンキュウ
|
Creator | |
Source Title |
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
|
Volume | 11 |
Start Page | 13 |
End Page | 17 |
Journal Identifire |
ISSN 05869943
|
Descriptions |
^1H NMR spectra of amine borane, <(CH_3)>_<3-n> H_nN・BH_3 and amine boron trifluoride, <(CH_3)>_<3-n>H_nN・BF_3 adducts were observed. ^1H chemical shifts of methyl groups occur at a higher field as the methyl group successively substituted for hydrogen on nitrogen. With respect to trimethylamine, both BH_3 and BF_3 bases are considered to be comparable acids. These results lead to a good relation between chemical shifts in BF_3 group and variations in structure on amine boron trifluoride adducts.
|
Language |
eng
|
Resource Type | departmental bulletin paper |
Publisher |
島根大学教育学部
The Faculty of Education Shimane University
|
Date of Issued | 1977-12-25 |
Access Rights | open access |
Relation |
[NCID] AN00107941
|