| File | |
| Title |
γ線照射されたBF_3単結晶に生じたBF_2 radicalのESR研究
|
| Title |
The ESR Study of the BF_2 Radical Produced in the γ-Irradiated Single Crystal of BF_3
|
| Title Transcription |
γセン ショウシャ サレタ BF_3 タンケッショウ ニ ショウジタ BF_2 radical ノ ESR ケンキュウ
|
| Creator | |
| Source Title |
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
|
| Volume | 9 |
| Start Page | 19 |
| End Page | 27 |
| Journal Identifire |
ISSN 05869943
|
| Descriptions |
Abstract
ESR spectra of the radicals produced in polycrystal and single crystal of BF_3 under γ-irradiation at 77 K were investigated. From analyses of these spectra, the radicals were identified as BF_3- and BF_2 radicals, respectively. ESR parameters of these radicals were the very same with those reported in literatures. Furthermore, the analyses showed that an interesting long-range interaction of the BF_2 radical with the nearest neighboring two molecules is involved and the distance between the BF_2 radical and the nearest neighboring fluorine atom is ca. 2.8 Å.
|
| Language |
eng
|
| Resource Type | departmental bulletin paper |
| Publisher |
島根大学教育学部
The Faculty of Education Shimane University
|
| Date of Issued | 1975-12-25 |
| Access Rights | open access |
| Relation |
[NCID]
AN00107941
|