File | |
Title |
γ線照射されたBF_3単結晶に生じたBF_2 radicalのESR研究
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Title |
The ESR Study of the BF_2 Radical Produced in the γ-Irradiated Single Crystal of BF_3
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Title Transcription |
γセン ショウシャ サレタ BF_3 タンケッショウ ニ ショウジタ BF_2 radical ノ ESR ケンキュウ
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Creator | |
Source Title |
島根大学教育学部紀要. 自然科学
Memoirs of the Faculty of Education, Shimane University. Natural science
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Volume | 9 |
Start Page | 19 |
End Page | 27 |
Journal Identifire |
ISSN 05869943
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Descriptions |
ESR spectra of the radicals produced in polycrystal and single crystal of BF_3 under γ-irradiation at 77 K were investigated. From analyses of these spectra, the radicals were identified as BF_3- and BF_2 radicals, respectively. ESR parameters of these radicals were the very same with those reported in literatures. Furthermore, the analyses showed that an interesting long-range interaction of the BF_2 radical with the nearest neighboring two molecules is involved and the distance between the BF_2 radical and the nearest neighboring fluorine atom is ca. 2.8 Å.
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Language |
eng
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Resource Type | departmental bulletin paper |
Publisher |
島根大学教育学部
The Faculty of Education Shimane University
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Date of Issued | 1975-12-25 |
Access Rights | open access |
Relation |
[NCID] AN00107941
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