木質材料の改良に関する研究(第16報) : 木材中でラジカル重合したポリメタクリル酸メチルの立体規則性

島根大学農学部研究報告 Volume 9 Page 73-77 published_at 1975-12-15
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Title
木質材料の改良に関する研究(第16報) : 木材中でラジカル重合したポリメタクリル酸メチルの立体規則性
Title
Studies on the Improvement of Wooden Materials(XVI) : Stereoregularity of Poly(Methyl Methacrylate)Formed by Radical Polymerization in Wood
Title Transcription
モクシツ ザイリョウ ノ カイリョウ ニ カンスル ケンキュウ ダイ16ホウ モクザイチュウ デ ラジカル ジュウゴウシタ ポリ メタクリルサン メチル ノ リッタイ キソクセイ
Creator
Onishi Hirotsugu
Jodai Susumu
Goto Teruo
Source Title
島根大学農学部研究報告
Bulletin of the Faculty of Agriculture, Shimane University
Volume 9
Start Page 73
End Page 77
Journal Identifire
ISSN 0370940X
Descriptions
The stereoregularity of poly (methyl methacrylate) (PMMA) polymerized in Karamatsu (Larix leptolepis GORDON) and Yellow seraya (Shorea faguetiana HEIM), using benzoyl peroxide as an initiator was investigated. The homopolymer and the grafted polymer onto cellulose and lignin were isolated from the wood-plastic combination, and their stereoregularities were quantitatively determined with a 100 MHZ NMR spectrometer. The stereoregularities of the grafted polymer onto cellulose and lignin were different from that of PMMA which was formed in ordinary radical polymerization. The stereoregularities of the grafted polymer onto wood components were numerically almost equal, but that of the grafted polymer onto lignin for Yellow seraya. Based on the experimental results, the effect of wood components on the stereoregularity of the polymer which was formed in wood was discussed.
Language
jpn
Resource Type departmental bulletin paper
Publisher
島根大学農学部
Shimane University, Faculty of Agriculture
Date of Issued 1975-12-15
Access Rights open access
Relation
[NCID] AN00108015