Phototropin-Inspired Chemoselective Synthesis of Unsymmetrical Disulfides: Aerobic Oxidative Heterocoupling of Thiols Using Flavin Photocatalysis

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ID	53852
ファイル	Phototropin-Inspired Chemoselective Synthesis of Unsymmetrical Disulfides: Aerobic Oxidative Heterocoupling of Thiols Using Flavin Photocatalysis 934 KB
言語	英語
著者	Oka, Marina Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan Katsube, Daichi Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan 辻剛志飯田拡基
内容記述（抄録等）	Inspired by the photochemical mechanism of a plant blue-light receptor, a unique flavin-based photocatalytic system was developed for the chemoselective heterocoupling of two different thiols, which enabled the facile synthesis of unsymmetrical disulfides. Owing to the redox- and photo-organocatalysis of flavin, the coupling reaction took place under mild metal-free conditions and visible light irradiation with the use of air, which is recognized as the ideal green oxidant.
主題	Disulfides Flavins Thiols,Adducts Heterocouplings
掲載誌名	Organic Letters
巻	22
号	23
開始ページ	9244
終了ページ	9248
ISSN	1523-7060
発行日	2020-12-04
DOI	10.1021/acs.orglett.0c03458
出版者	American Chemical Society
資料タイプ	学術雑誌論文
ファイル形式	PDF
著者版/出版社版	著者版
業績ID	38961
部局	総合理工学部