Coupled Flavin-Iodine Redox Organocatalysts: Aerobic Oxidative Transformation from N-Tosylhydrazones to 1,2,3-Thiadiazoles
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この文献の参照には次のURLをご利用ください : https://ir.lib.shimane-u.ac.jp/49156
| ID | 49156 |
| ファイル | |
| 言語 |
英語
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| 属性 |
LETTER
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| 著者 |
Ishikawa, Tatsuro
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
Kimura, Maasa
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
Kumoi, Takuma
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
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| 内容記述（抄録等） | A bioinspired two-component redox organocatalyst system using 1,10-bridged flavinium and NH4I was developed to perform environmentally friendly aerobic oxidative ring formation of 1,2,3-thiadiazoles from N-tosylhydrazones and sulfur. The redox organocatalysis of the flavinium promoted the iodine-catalyzed system without the use of any sacrificial reagents, except for environmentally benign molecular oxygen.
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| 主題 | redox organocatalyst
flavin
iodine
aerobic oxidation
thiadiazole
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| 掲載誌名 |
ACS Catalysis
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| 巻 | 7
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| 号 | 8
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| 開始ページ | 4986
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| 終了ページ | 4989
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| ISSN | 2155-5435
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| 発行日 | 2017-6-29
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| DOI | |
| 出版者 | American Chemical Society
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| 資料タイプ |
学術雑誌論文
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| ファイル形式 |
PDF
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| 関連情報 | |
| 権利関係 | Copyright © 2017 American Chemical Society
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| 著者版/出版社版 |
著者版
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| 業績ID | e32743
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| 部局 |
総合理工学部
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| 備考 | ACS Catal. 2017, 7, 8, 4986-4989 Publication Date:June 29, 2017
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