Coupled Flavin-Iodine Redox Organocatalysts: Aerobic Oxidative Transformation from N-Tosylhydrazones to 1,2,3-Thiadiazoles
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Use this link to cite this item : https://ir.lib.shimane-u.ac.jp/49156
| ID | 49156 |
| File | |
| language |
eng
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| Attribute |
LETTER
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| Author |
Ishikawa, Tatsuro
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
Kimura, Maasa
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
Kumoi, Takuma
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
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| Description | A bioinspired two-component redox organocatalyst system using 1,10-bridged flavinium and NH4I was developed to perform environmentally friendly aerobic oxidative ring formation of 1,2,3-thiadiazoles from N-tosylhydrazones and sulfur. The redox organocatalysis of the flavinium promoted the iodine-catalyzed system without the use of any sacrificial reagents, except for environmentally benign molecular oxygen.
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| Subject | redox organocatalyst
flavin
iodine
aerobic oxidation
thiadiazole
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| Journal Title |
ACS Catalysis
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| Volume | 7
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| Issue | 8
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| Start Page | 4986
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| End Page | 4989
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| ISSN | 2155-5435
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| Published Date | 2017-6-29
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| DOI | |
| Publisher | American Chemical Society
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| NII Type |
Journal Article
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| Format |
PDF
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| Relation | |
| Rights | Copyright © 2017 American Chemical Society
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| Text Version |
著者版
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| Gyoseki ID | e32743
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| OAI-PMH Set |
Faculty of Science and Engineering
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| Remark | ACS Catal. 2017, 7, 8, 4986-4989 Publication Date:June 29, 2017
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