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タイトルヨミ
サクサン ブチル ニ ヨル クローム ノ チュウシュツ ト ソノ テイリョウ ニ ツイテ
日本語以外のタイトル
On the Extraction of Cr with Butylacetate and its Measuring
ファイル
言語
日本語
著者
山本 作次郎
内容記述(抄録等)
There are a few studies on the extractions of metals from their inorganic salt solutions with immissible organic solvents ; it is familiar to extract Cr as a perchromate from its acidic solution with diethylether or ethylacetate (M. D. Foster , U. S. Geol. Survey Bull., 950. 15 (1946) ). We tried with butylacetate, extracting the perchromate from the solutions which are obtained, oxidizing CrCl_3 solution witn NaOH and Na_2 O_2 or with NH_4 OH and H_2 O_2 in various concentrations of HCl and H_2 O_2.
The extracting power (%) is calculated mediately, measuring the residual Cr in the apueous solution after extraction ; in both cases, the 30% and 8% of Cr are extracted respectively. In the quantitative analysis of the residual solution, it is done by the Mohr' s salt-KMnO_4 method, giving that the end points of titration witn a normal solution of KMnO_4 are not so clear owing to the obscuring by the biproductive substances such as NaCl and Na_2SO_4 or NH_4Cl and (NH_4)_2SO_4, and found that the color change at the end point of titration is puitely sharp, when the original CrCl_3 solutions are treated with NH_4 OH and H_2 O_2 producing (NH_4)_2 CrO_4 and the residual solutions after extraction are evaporated and calcined, rejecting organic solvent and the most part of NH_4Cl and (NH_4)_2SO_4.
Titrations should be done at the temperature not over 30℃, using acidic KMnO_4 solution of 0. 12-N H_2SO_4.
掲載誌名
島根大学論集. 自然科学
6
開始ページ
52
終了ページ
57
ISSN
04886542
発行日
1956-02-21
NCID
AN0010814X
出版者
島根大学
出版者別表記
Shimane University
資料タイプ
紀要論文
部局
総合理工学部
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