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ファイル
言語
英語
著者
Oka, Marina Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan
Katsube, Daichi Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan
内容記述(抄録等)
Inspired by the photochemical mechanism of a plant blue-light receptor, a unique flavin-based photocatalytic system was developed for the chemoselective heterocoupling of two different thiols, which enabled the facile synthesis of unsymmetrical disulfides. Owing to the redox- and photo-organocatalysis of flavin, the coupling reaction took place under mild metal-free conditions and visible light irradiation with the use of air, which is recognized as the ideal green oxidant.
主題
Disulfides
Flavins
Thiols,Adducts
Heterocouplings
掲載誌名
Organic Letters
22
23
開始ページ
9244
終了ページ
9248
ISSN
1523-7060
発行日
2020-12-04
DOI
出版者
American Chemical Society
資料タイプ
学術雑誌論文
ファイル形式
PDF
著者版/出版社版
著者版
業績ID
38961
部局
総合理工学部