ID | 52539 |
ファイル | |
言語 |
英語
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著者 |
Tanimoto, Kazumasa
Aerobic Oxidative Sulfenylation of Pyrazolones and Pyrazoles Catalyzed by Metal-Free Flavin–Iodine Catalysis
Ohkado, Ryoma
Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
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内容記述(抄録等) | Two-component metal-free catalytic oxidative sulfenylation of pyrazolones with thiols has been achieved using the biomimetic flavin and iodine. The methodology is mild and eco-friendly, proceeds in the presence of air or molecular oxygen (1 atm) as the sole sacrificial reagent, and generates water as the only byproduct. The methodology was also extended to the sulfenylation of pyrazoles and electron-rich benzenes and afforded a series of thioethers in good yields.
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掲載誌名 |
The Journal of Organic Chemistry
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巻 | 84
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号 | 22
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開始ページ | 14980
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終了ページ | 14986
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ISSN | 0022-3263
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ISSN(Online) | 1520-6904
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発行日 | 2019-10-22
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DOI | |
出版者 | American Chemical Society
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資料タイプ |
学術雑誌論文
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ファイル形式 |
PDF
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関連情報 | |
著者版/出版社版 |
著者版
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業績ID | e37157
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部局 |
総合理工学部
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