Aerobic Oxidative C–H Azolation of Indoles and One-Pot Synthesis of Azolyl Thioindoles by Flavin–Iodine-Coupled Organocatalysis

ダウンロード数 : ? 件

この文献の参照には次のURLをご利用ください : https://ir.lib.shimane-u.ac.jp/53853

ID	53853
ファイル	Aerobic Oxidative C–H Azolation of Indoles and One-Pot Synthesis of Azolyl Thioindoles by Flavin–Iodine-Coupled Organocatalysis 1.28 MB
言語	英語
著者	Tanimoto, Kazumasa Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan Okai, Hayaki Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan Oka, Marina Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan Ohkado, Ryoma Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan 飯田拡基
内容記述（抄録等）	The aerobic oxidative cross-coupling of indoles with azoles driven by flavin-iodine-coupled organocatalysis has been developed for the green synthesis of 2-(azol-1-yl)indoles. The coupled organocatalytic system enabled the one-pot three-component synthesis of 2-azolyl-3-thioindoles from indoles, azoles, and thiols in an atom-economical manner by utilizing molecular oxygen as the only sacrificial reagent.
主題	Oxidation reactions Flavins Chemical synthesis,Indoles Cross coupling reaction
掲載誌名	Organic Letters
巻	23
号	6
開始ページ	2084
終了ページ	2088
ISSN	1523-7060
ISSN（Online）	1523-7052
発行日	2021-03-19
DOI	10.1021/acs.orglett.1c00241
出版者	American Chemical Society
資料タイプ	学術雑誌論文
ファイル形式	PDF
著者版/出版社版	著者版
業績ID	38962
部局	総合理工学部