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language
eng
Author
Oka, Marina Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan
Katsube, Daichi Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504 Japan
Description
Inspired by the photochemical mechanism of a plant blue-light receptor, a unique flavin-based photocatalytic system was developed for the chemoselective heterocoupling of two different thiols, which enabled the facile synthesis of unsymmetrical disulfides. Owing to the redox- and photo-organocatalysis of flavin, the coupling reaction took place under mild metal-free conditions and visible light irradiation with the use of air, which is recognized as the ideal green oxidant.
Subject
Disulfides
Flavins
Thiols,Adducts
Heterocouplings
Journal Title
Organic Letters
Volume
22
Issue
23
Start Page
9244
End Page
9248
ISSN
1523-7060
Published Date
2020-12-04
DOI
Publisher
American Chemical Society
NII Type
Journal Article
Format
PDF
Text Version
著者版
Gyoseki ID
38961
OAI-PMH Set
Faculty of Science and Engineering