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Title Transcription
ハロゲンカ スズ 2 ノ サクカゴウブツ ノ メスバウア ケンキュウ
Title Alternative (English)
Mossbauer Study of the Complex Compounds of Tin(II) Halides
File
language
eng
Author
Mishima, Mitsuo
Idogaki, Masatoshi
Negita, Hisao
Description
Mossbauer spectra of <119>^Sn were observed in tin (II) chloride, bromide and their complexes of the types MSnX^3・H_20 and M_2SnX_4・H_20, where M = NH_4, K or Cs, and X = Cl or Br. All of the complexes exhibited small quadrupole splittings. In comparison with the parent halides SnX_2, the complex chlorides have smaller isomer shifts, whereas this is not the case for the complex bromides. The isomer shift was related to the strength of the ligand field, and the decrease in the isomer shift was interpreted by s-p mixing due to the field stabilization.
Journal Title
Memoirs of the Faculty of Literature and Science, Shimane University. Natural sciences
Volume
7
Start Page
73
End Page
77
ISSN
03709434
Published Date
1974-03-10
NCID
AN0010806X
Publisher
島根大学文理学部
Publisher Aalternative
The Faculty of Literature and Science, Shimane University
NII Type
Departmental Bulletin Paper
OAI-PMH Set
Faculty of Science and Engineering
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