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File
language
eng
Author
Mishima, Mitsuo
Description
The ^<35>Cl NQR of tetrachlorothiophene has been observed and the Zeeman effect on a single crystal has been examined. This compound yields four lines at room temperature. These lines are divided into two distinct groups, i.e., two lower frequency lines (36.90 and 36.93 MHz) and two higher frequency ones (37.63 and 37.68 MHz). On the basis of Zeeman analysis, the lower lines are assigned to the Cl atoms at the 3- and 4-positions and the higher ones to those at the 2- and 5-positions. The angles between the C-Cl bonds have been deduced and it has been revealed that four C-Cl bonds in the molecule are nearly coplanar. From the distribution of the zero-splitting loci, it has been determined that the crystal of TCT belongs to an orthorhombic system.
Subject
NQR
Zeeman effect
Tetrachlorothiophene
Journal Title
Bulletin of Shimane Medical University
Volume
12
Start Page
85
End Page
92
ISSN
03879097
Published Date
1989-12-01
NCID
AN00107602
Publisher
島根医科大学
NII Type
Departmental Bulletin Paper
Format
PDF
Text Version
出版社版
OAI-PMH Set
Faculty of Medicine
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