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language
eng
Author
Ohkado, Ryoma Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
Ishikawa, Tatsuro Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan
Description
A unique coupled redox organocatalysis system using flavin and iodine catalysts efficiently promoted the metal-free aerobic oxidative direct sulfenylation of indoles with thiols at ambient temperature without any sacrificial reagents, except environmentally benign molecular oxygen. Biomimetic flavin catalysis plays multiple roles in aerobic oxidative transformations, not only regenerating I2 from in situ generated I−, but also converting thiols into disulfides.
Journal Title
Green Chemistry
Volume
20
Start Page
984
End Page
988
ISSN
1463-9262
ISSN(Online)
1463-9270
Published Date
2018-2-5
DOI
Publisher
The Royal Society of Chemistry
NII Type
Journal Article
Format
PDF
Relation
Text Version
著者版
Gyoseki ID
e33058
OAI-PMH Set
Faculty of Science and Engineering
Remark
Green Chem., 2018,20, 984-988
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